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BioEnergy Center
Applied Energy Center
CAS Key Laboratory of Biobased Materials
Location: Home>Research>Research System>Applied Energy Center>Heterogeneous Catalytic Conversion
Heterogeneous Catalytic Conversion

 

Group Leader

Prof. LI received his Ph.D. degree in Technical Chemistry at TU München in 2004. Prof. LI worked first as postdoctoral researcher at UC Berkeley from 2005 to 2007 and then as “Senior Scientist” at TU München from 2007 to 2010. His main research interest is heterogeneous catalytic conversion of substantially available raw materials to modern energy products. He is also extensively explore the reaction mechanisms, micro-kinetics and catalytically active surface structures. In recent 5 years, Prof. LI has more than 20 publications at academic journals. 

More... 

lixb@qibebt.ac.cn 

 

+86-532-80662757

 

Group Members

LIN Sen 

Associate Professor 

linsen@qibebt.ac.cn 

XIN Hongchuan 

Associate Professor 

xinhc@qibebt.ac.cn 

GUO Peng 

Assistant Professor 

guopeng@qibebt.ac.cn 

SONG Liang 

Assistant Professor 

songliang@qibebt.ac.cn 

LI Guangci 

Assistant Professor 

ligc@qibebt.ac.cn 

ZHANG Chuanhui 

Assistant Professor 

zhang_ch@qibebt.ac.cn 

CAO Xing 

Postdoctoral Researcher 

caoxing@qibebt.ac.cn 

CHEN Lei 

Research Assistant 

chenlei@qibebt.ac.cn 

LI Hong 

Research Assistant 

lihong@qibebt.ac.cn 

 

Research Focus 

  

Research Activities 

1. Aviation biofuel from bioethanol 

The aim of this project is to develop a continuous reacting unit that converts diluted bioethanol to Jet Fuel, a blend of hydrocarbons with 1) straight and branched alkanes, 2) naphthenes and 3) aromatics. The bioethanol is dehydrated to ethylene under atmospheric pressure. A part of the ethylene is oligomerized to olefins with 9-16 carbon chains, followed by hydrotreating to produce the alkanes and naphthenes. The rest is converted to aromaticswith 6-9 carbon chains. 

 

2. Oxidative dehydrogenation of lactic acid to pyruvic acid 

The optimized Mo0.61V0.31Nb0.08Ox gave the high selectivity of pyruvic acid (Fig. a). In addition, the selectivity of pyruvic acid decreased with increasing lactic acid conversion, as a result of secondary oxidation of tri-carbon acids to acetic acid and carbon dioxide (Fig. b). Throughout the catalytic mechanism, amorphous [Mo(V,Nb)]5O14 domains showed to be more active, overall, than α-MoO3 and VO2 crystal phases (Figs. c, d and e). 

 

3. Emission treatment system 

To design highly efficient SOx scrubber and NO conversion catalysts for the exhaust gas treatment for ship or power plant with low pressure drop and operation cost, to meet the new strict international exhaust emission standards, sponsored by Qingdao Municipal Science and Technology Commission.

Selected Publications

2014: 

    Hongchuan Xin, Xiangping Li, Yuan Fang, Xianfeng Yi, Wenhui Hu, Yueying Chu, Feng Zhang, Anmin Zheng, Hongpeng Zhang, Xuebing Li, Catalytic Dehydration of Ethanol over Post-treated ZSM-5 Zeolites, J. Catal., 2014, 312, 204-215. 

    Mingdong Zhou, Wenye Meng, Yang Li, Qiang Wang, Xuebing Li, Shuliang Zang, Extractive and Catalytic Oxidative Desulfurization of Gasoline by Methyltrioxorhenium in Ionic Liquids, Energy Fuels, 2014, 28, 516-521. 

    Sen Lin, Lei Shi, Hongpeng Zhang, Na Zhang, Xianfeng Yi, Anmin Zheng, Xuebing Li, Tuning the Pore Structure of Plug-containing Al-SBA-15 by Post-treatment and its Selectivity for C16 Olefin in Ethylene Oligomerization, Micropor. Mesopor. Mater., 2014, 184, 151-161. 

    Lei Chen, Hongchuan Xin, Yuan Fang, Cong Zhang, Feng Zhang, Xing Cao, Chunhui Zhang, Xuebing Li, Application of Metal Oxide Heterostructures in Arsenic Removal from Contaminated Water, J. Nanomater., 2014, 2014, Article ID 793610. 

    Cong Zhang, Jing Xing, Liang Song, Hongchuan Xin, Sen Lin, Lishu Xing, Xuebing Li, Aqueous-phase Hydrodeoxygenation of Lignin Monomer Eugenol: Influence of Si/Al Ratio of HZSM-5 on Catalytic Performances, Catal. Today, 2014, 10.1016/j.cattod.2014.01.021. 

2013: 

    Lei Shi, Yan Xu, Na Zhang, Sen Lin, Xiangping Li, Peng Guo, Xuebing Li, Direct Synthesis of Al-SBA-15 Containing Aluminosilicate Species Plugs in an Acid-free Medium and Structural Adjustment by Hydrothermal Post-treatment, J. Solid State Chem., 2013, 203, 281-290. 

    Guangci Li, Xinlu Lu, Zhe Tang, Yunqi Liu, Xuebing Li, Chenguang Liu, Preparation of NiMo/γ-Al2O3 Catalysts with Large Pore Size for Vacuum Residue Hydrotreatment, Mater. Res. Bull., 2013, 48, 4526-4530. 

2012: 

    Ningning Chu, Yan Xu, Yujiu Ma, Jianxun Wang, Xuebing Li, Lisheng Wang, Fuel Properties of a Two-Phase Biodiesel Emulsion, Adv. Mater. Res., 2012, 418-420, 254-259. 

 
 

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